2S-hydroxy-34-dehydroneomajucin (cmpd 6) (0.26Hz/7)


Gaussian numbering
1H-1H Js
 -ppm- -#-   H22   H23   H24   H25   H27   H28   H29   H30   H31   H32   H33   H34   H35   H36   H37   H38   H39   H40   
  2.31 H22
  2.20 H23 -14.7
  4.44 H24   4.2   1.6
  2.00 H25    -     -     - 
  3.86 H27    -     -     -     - 
  6.33 H28   0.8    -     -     -     - 
  3.88 H29    -     -     -     -     -     - 
  3.90 H30    -     -     -     -     -     -  -10.7
  1.37 H31    -     -     -     -     -     -     -    1.1
  1.37 H32    -     -     -     -     -     -     -    1.1    - 
  1.37 H33    -     -     -     -     -     -     -    1.1    -     - 
  2.50 H34    -     -     -     -     -     -     -     -     -     -     - 
  3.61 H35    -     -     -     -     -     -     -     -     -     -     -     - 
  1.18 H36    -     -     -    7.3    -     -     -     -     -     -     -     -     - 
  1.18 H37    -     -     -    7.3    -     -     -     -     -     -     -     -     -     - 
  1.18 H38    -     -     -    7.3    -     -     -     -     -     -     -     -     -     -     - 
  2.84 H39    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  4.29 H40    -     -     -    5.9    -    3.3    -     -     -     -     -     -     -     -     -     -    6.4

13C-1H Js
 -ppm- -#-   H22   H23   H24   H25   H27   H28   H29   H30   H31   H32   H33   H34   H35   H36   H37   H38   H39   H40   
 30.32 C1  131.6 136.3  -2.2   5.1   1.5    -     -     -     -     -     -     -     -     -     -     -     -     - 
 51.30 C2   -3.1  -3.8   5.4  -3.9  -3.3   9.1    -     -     -     -     -     -     -    4.3   4.3   4.3    -    6.8
146.89 C3    6.0   1.5    -    0.9   5.8   3.0   0.8   2.7   4.3   4.3   4.3    -     -     -     -     -     -    5.8
 44.89 C4     -     -    3.8    -     -    2.9  -2.4    -   -3.7  -3.7  -3.7    -     -     -     -     -     -     - 
 76.22 C5    5.3   1.0  -4.1    -     -     -    3.7    -    3.7   3.7   3.7    -     -     -     -     -     -     - 
 80.72 C6   -4.4  -1.5 162.8    -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
 49.79 C7    1.0   2.7    -  128.7   2.4   5.9    -     -     -     -     -     -     -   -4.1  -4.1  -4.1    -   -1.3
 68.23 C8    3.8  10.6    -    4.8 146.1  -0.9    -     -     -     -     -     -     -     -     -     -     -     - 
140.19 C10    -     -     -     -     -  166.8    -     -     -     -     -     -     -     -     -     -     -   -3.3
 73.28 C11    -     -     -     -     -   -1.4 156.7 153.8   5.5   5.5   5.5    -     -     -     -     -     -    0.7
 20.78 C12    -     -     -     -     -     -    5.8   6.0 131.5 131.5 131.5    -     -     -     -     -     -     - 
175.79 C16    -     -    5.7   0.7  -4.7    -     -     -     -     -     -     -     -     -     -     -     -     - 
 74.09 C18    -     -     -   -2.9    -    4.9    -     -     -     -     -     -     -    4.2   4.2   4.2    -  151.4
178.81 C20   0.7    -    1.5    -     -     -    5.4   1.3    -     -     -     -     -     -     -     -     -     - 
  8.34 C26    -     -     -   -4.1    -     -     -     -     -     -     -     -     -  128.5 128.5 128.5    -     - 
 -ppm- -#-   H22   H23   H24   H25   H27   H28   H29   H30   H31   H32   H33   H34   H35   H36   H37   H38   H39   H40   
1H data (JH-H abs sorted)

6.33 (3.3, 0.8)
4.44 (4.2, 1.6)
4.29 (6.4, 5.9, 3.3)
3.90 (10.7, 1.1, 1.1, 1.1)
3.88 (10.7)
3.86
3.61
2.84 (6.4)
2.50
2.31 (14.7, 4.2, 0.8)
2.20 (14.7, 1.6)
2.00 (7.3, 7.3, 7.3, 5.9)
1.37 (1.1)
1.18 (7.3)
13C data
 20 178.8 (5.4, 1.5, 1.3, 0.7)
 16 175.8 (5.7, -4.7, 0.7)
  3 146.9 (6.0, 5.8, 5.8, 4.3)
 10 140.2 (166.8, -3.3)
  6  80.7 (162.8, -4.4, -1.5)
  5  76.2 (5.3, -4.1, 3.7, 3.7)
 18  74.1 (151.4, 4.9, 4.2, 4.2)
 11  73.3 (156.7, 153.8, 5.5, 5.5)
  8  68.2 (146.1, 10.6, 4.8, 3.8)
  2  51.3 (9.1, 6.8, 5.4, 4.3)
  7  49.8 (128.7, 5.9, -4.1, -4.1)
  4  44.9 (3.8, -3.7, -3.7, -3.7)
  1  30.3 (136.3, 131.6, 5.1, -2.2)
 12  20.8 (131.5, 131.5, 131.5, 6.0)
 26   8.3 (128.5, 128.5, 128.5, -4.1)