bacaryolane C (0.29Hz/17)


FRACTIONS (manually entered): 0.357 0.386 0.257 (major structure is shown)
Rel. DFT Energies (kcal/mol): 0.218 0.000 0.833
Gaussian numbering
1H-1H Js
 -ppm- -#-   H5    H8    H11   H12   H13   H14   H15   H16   H17   H18   H20   H24   H25   H27   H31   H32   H33   H34   H35   H37   H38   H39   H40   H41   H42   H43   
  1.21 H5 
  1.68 H8     - 
  2.07 H11    -   11.4
  1.58 H12    -     -    8.5
  2.06 H13    -     -   10.4  -9.9
  1.21 H14    -     -     -     -     - 
  1.21 H15    -     -     -     -     -     - 
  1.27 H16    -     -     -     -    0.7    -     - 
  1.27 H17    -     -     -     -    0.7    -     -     - 
  1.27 H18    -     -     -     -    0.7    -     -     -     - 
  3.86 H20    -    8.1    -     -     -     -     -     -     -     - 
  1.11 H24    -     -     -     -     -     -     -     -     -     -    7.8
  1.86 H25    -     -     -     -     -     -     -     -     -     -    4.3 -13.8
 -0.38 H27    -     -     -     -     -     -     -     -     -     -    4.5    -     - 
  0.75 H31    -     -     -     -     -     -     -     -     -     -     -     -    1.0    - 
  2.12 H32    -     -     -     -     -     -     -     -     -     -     -     -     -     -  -13.1
 -0.30 H33    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  1.86 H34    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -    2.5    - 
  1.01 H35    -     -    0.9    -     -     -     -     -     -     -     -     -     -     -     -     -     -  -12.6
  1.55 H37    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -    1.7    -    0.8    - 
  1.14 H38    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -  -13.5
  1.77 H39    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -    4.5   5.8   5.5   4.7
  1.09 H40    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  1.76 H41    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -    5.4   9.9   4.2  10.9 -14.0    - 
  1.09 H42    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  1.09 H43    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 

13C-1H Js
 -ppm- -#-   H5    H8    H11   H12   H13   H14   H15   H16   H17   H18   H20   H24   H25   H27   H31   H32   H33   H34   H35   H37   H38   H39   H40   H41   H42   H43   
 35.85 C1   -4.0  -3.8   1.9  -2.5  -3.6  -4.0  -4.0  -3.9  -3.9  -3.9   2.4    -    0.6    -     -     -     -     -     -     -     -     -     -     -     -     - 
 52.26 C2    5.1 129.6  -4.4  10.4   1.3   5.1   5.1   3.9   3.9   3.9  -1.9   3.9   4.6    -    0.7    -     -     -     -     -     -     -     -     -     -     - 
 29.49 C3  125.3   5.1    -    1.1   5.0 125.3 125.3   4.9   4.9   4.9    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
 19.15 C4    4.5   3.7    -    4.3   5.0   4.5   4.5 126.7 126.7 126.7    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
 39.15 C6     -   -5.0 130.8  -2.9  -4.8    -     -     -     -     -    2.2    -     -     -    6.3   2.1    -    3.4   5.7    -     -     -     -     -     -     - 
 71.49 C7     -   -4.0   4.3   2.5    -     -     -     -     -     -  142.7  -5.4  -3.7    -     -     -     -     -     -     -     -     -     -     -     -     - 
 69.80 C9     -    3.6  -1.3   0.8   3.0    -     -     -     -     -     -     -     -     -   -4.4  -4.7    -   -4.5  -4.7    -     -    6.3    -    2.4    -     - 
 32.69 C10   5.2   1.9  -5.0 136.5 137.5   5.2   5.2   5.0   5.0   5.0    -     -     -     -    0.8    -     -     -     -     -     -     -     -     -     -     - 
 48.28 C19    -    2.6    -     -     -     -     -     -     -     -   -2.2 124.4 127.1    -    6.1   2.6    -     -     -    3.4   5.3    -    4.4    -    4.4   4.4
 40.46 C22    -     -    4.7    -     -     -     -     -     -     -     -     -     -     -    2.8   5.3    -  131.1 123.5   6.1   3.2  -3.7    -   -3.5    -     - 
 36.99 C26    -     -     -     -     -     -     -     -     -     -    3.0  -3.9  -3.5    -   -3.9  -3.6    -     -     -   -3.3  -3.5   6.5  -3.4   3.2  -3.4  -3.4
 48.79 C28    -     -    1.1    -     -     -     -     -     -     -     -    3.0   5.0    -  122.1 131.5    -    5.9   1.9   4.6   2.2    -    4.5    -    4.5   4.5
 35.72 C29    -     -     -     -     -     -     -     -     -     -     -    4.7   3.3    -    1.4   5.9    -    5.7   2.8 127.6 125.3  -3.9   5.0  -3.7   5.0   5.0
 32.87 C30    -     -     -     -     -     -     -     -     -     -     -    4.3   3.6    -    4.0   1.5    -     -     -    2.6   4.5    -  126.8    -  126.8 126.8
 21.75 C36    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -   -3.3  -3.9  -3.3  -3.9 128.7    -  126.6    -     - 
 -ppm- -#-   H5    H8    H11   H12   H13   H14   H15   H16   H17   H18   H20   H24   H25   H27   H31   H32   H33   H34   H35   H37   H38   H39   H40   H41   H42   H43   
1H data (JH-H abs sorted)

3.86 (8.1, 7.8, 4.5, 4.3)
2.12 (13.1, 2.5, 1.7)
2.07 (11.4, 10.4, 8.5, 0.9)
2.06 (10.4, 9.9, 0.7, 0.7)
1.86 (13.8, 4.3, 1.0)
1.86 (12.6, 4.5, 2.5, 0.8)
1.77 (5.8, 5.5, 4.7, 4.5)
1.76 (10.9, 9.9, 5.4, 4.2)
1.68 (11.4, 8.1)
1.58 (9.9, 8.5)
1.55 (13.5, 5.5, 1.7, 0.8)
1.27 (0.7)
1.21
1.14 (13.5, 10.9, 4.7)
1.11 (13.8, 7.8)
1.09
1.01 (12.6, 9.9, 5.8, 0.9)
0.75 (13.1, 1.0)
-0.30
-0.38 (4.5)
13C data
  7  71.5 (142.7, -5.4, 4.3, -4.0)
  9  69.8 (6.3, -4.7, -4.7, -4.5)
  2  52.3 (129.6, 10.4, 5.1, 5.1)
 28  48.8 (131.5, 122.1, 5.9, 5.0)
 19  48.3 (127.1, 124.4, 6.1, 5.3)
 22  40.5 (131.1, 123.5, 6.1, 5.3)
  6  39.1 (130.8, 6.3, 5.7, -5.0)
 26  37.0 (6.5, -3.9, -3.9, -3.6)
  1  35.9 (-4.0, -4.0, -4.0, -3.9)
 29  35.7 (127.6, 125.3, 5.9, 5.7)
 30  32.9 (126.8, 126.8, 126.8, 4.5)
 10  32.7 (137.5, 136.5, 5.2, 5.2)
  3  29.5 (125.3, 125.3, 125.3, 5.1)
 36  21.7 (128.7, 126.6, -3.9, -3.9)
  4  19.1 (126.7, 126.7, 126.7, 5.0)