Gaussian numbering

¹H-¹H Js
 -ppm- -#-   H12   H13   H14   H15   H16   H18   H19   H20   H22   H25   H26   H27   H29   H30   H33   H34   H35   H36   H37   H38   
  1.51 H12
  1.83 H13 -13.9
  1.81 H14   3.2   3.1
  0.88 H15   3.8  14.9 -13.2
  1.24 H16    -     -    7.6  11.5
  6.94 H18    -     -     -     -     - 
  3.15 H19    -     -     -     -    1.2   4.6
  2.50 H20    -     -     -     -     -    1.0   3.9
  3.76 H22    -     -     -     -     -    1.1    -    7.2
  1.32 H25    -    0.7    -     -     -     -     -     -     - 
  1.32 H26    -    0.7    -     -     -     -     -     -     -     - 
  1.32 H27    -    0.7    -     -     -     -     -     -     -     -     - 
  5.64 H29    -     -     -     -     -     -     -     -     -     -     -     - 
  1.44 H30    -     -     -     -   10.2    -     -     -     -     -     -     -     - 
  0.99 H33    -     -     -     -     -     -     -     -     -     -     -     -     -    6.6
  0.99 H34    -     -     -     -     -     -     -     -     -     -     -     -     -    6.6    - 
  0.99 H35    -     -     -     -     -     -     -     -     -     -     -     -     -    6.6    -     - 
  1.11 H36    -     -     -     -     -     -     -     -     -     -     -     -     -    6.4    -     -     - 
  1.11 H37    -     -     -     -     -     -     -     -     -     -     -     -     -    6.4    -     -     -     - 
  1.11 H38    -     -     -     -     -     -     -     -     -     -     -     -     -    6.4    -     -     -     -     - 

¹³C-¹H Js
 -ppm- -#-   H12   H13   H14   H15   H16   H18   H19   H20   H22   H25   H26   H27   H29   H30   H33   H34   H35   H36   H37   H38   
199.84 C1     -     -     -     -    1.1  -1.6   2.0  -4.6  -4.7    -     -     -     -     -     -     -     -     -     -     - 
 33.21 C2   -2.8  -4.2   9.3   2.8    -   -1.2   4.8  -1.6  -0.7  -4.0  -4.0  -4.0    -     -     -     -     -     -     -     - 
163.75 C3     -     -     -     -     -    5.4  -0.8    -    4.4    -     -     -     -     -     -     -     -     -     -     - 
148.93 C4     -     -     -     -    5.8 168.3  -7.7   7.6   4.1    -     -     -     -     -     -     -     -     -     -     - 
 25.05 C6  131.1 128.2  -3.3  -4.1   1.2    -     -     -     -    4.5   4.5   4.5    -     -     -     -     -     -     -     - 
 25.58 C7   -3.4  -4.2 132.7 125.1  -3.8    -    3.1    -     -     -     -     -     -    1.7    -     -     -     -     -     - 
 45.25 C8    7.2   2.9  -2.9  -4.3 128.0   2.0  -5.0   1.3    -     -     -     -     -   -3.8   4.2   4.2   4.2   4.5   4.5   4.5
 45.44 C9     -     -    6.1   0.6  -3.0   4.6 136.9  -1.7    -     -     -     -     -    3.0    -     -     -     -     -     - 
 59.26 C10   3.0   0.9    -     -    4.2   6.1  -3.1 145.8   9.0   5.0   5.0   5.0    -     -     -     -     -     -     -     - 
 22.69 C11   6.1   4.0    -     -     -     -     -    4.0   3.6 127.8 127.8 127.8    -     -     -     -     -     -     -     - 
 32.94 C17    -     -    0.6   4.4  -4.0    -    5.1    -     -     -     -     -     -  125.2  -3.6  -3.6  -3.6  -3.5  -3.5  -3.5
 63.05 C21   1.2   5.2    -     -     -    6.9  -1.1   6.8 155.3   5.2   5.2   5.2    -     -     -     -     -     -     -     - 
133.34 C23    -     -     -     -     -   -0.7   6.4  -0.9  -4.3    -     -     -     -     -     -     -     -     -     -     - 
 19.65 C31    -     -     -     -    3.7    -     -     -     -     -     -     -     -   -3.4   5.3   5.3   5.3 126.2 126.2 126.2
 18.68 C32    -     -     -     -    1.8    -     -     -     -     -     -     -     -   -3.7 126.7 126.7 126.7   5.3   5.3   5.3
 -ppm- -#-   H12   H13   H14   H15   H16   H18   H19   H20   H22   H25   H26   H27   H29   H30   H33   H34   H35   H36   H37   H38

¹H data (J_H-H abs sorted)

6.94 (4.6, 1.1, 1.0)
5.64
3.76 (7.2, 1.1)
3.15 (4.6, 3.9, 1.2)
2.50 (7.2, 3.9, 1.0)
1.83 (14.9, 13.9, 3.1, 0.7)
1.81 (13.2, 7.6, 3.2, 3.1)
1.51 (13.9, 3.8, 3.2)
1.44 (10.2, 6.6, 6.6, 6.6)
1.32 (0.7)
1.24 (11.5, 10.2, 7.6, 1.2)
1.11 (6.4)
0.99 (6.6)
0.88 (14.9, 13.2, 11.5, 3.8)

¹³C data

  1 199.8 (-4.7, -4.6, 2.0, -1.6)
  3 163.7 (5.4, 4.4, -0.8)
  4 148.9 (168.3, -7.7, 7.6, 5.8)
 23 133.3 (6.4, -4.3, -0.9, -0.7)
 21  63.1 (155.3, 6.9, 6.8, 5.2)
 10  59.3 (145.8, 9.0, 6.1, 5.0)
  9  45.4 (136.9, 6.1, 4.6, 3.0)
  8  45.3 (128.0, 7.2, -5.0, 4.5)
  2  33.2 (9.3, 4.8, -4.2, -4.0)
 17  32.9 (125.2, 5.1, 4.4, -4.0)
  7  25.6 (132.7, 125.1, -4.2, -3.8)
  6  25.1 (131.1, 128.2, 4.5, 4.5)
 11  22.7 (127.8, 127.8, 127.8, 6.1)
 31  19.6 (126.2, 126.2, 126.2, 5.3)
 32  18.7 (126.7, 126.7, 126.7, 5.3)

kadcoccinine A (0.27Hz/3)