marilzanin (0.28Hz/19)

FRACTIONS (manually entered): 0.954 0.046 (major structure is shown)
Rel. DFT Energies (kcal/mol): 0.000 1.798
Gaussian numbering 
1H-1H Js
 -ppm- -#-   H10   H17   H18   H20   H21   H27   H28   H29   H30   H31   H32   H33   H34   H35   H36   H37   H38   H39   H40   
  4.07 H10
  4.33 H17    - 
  2.88 H18    -     - 
  4.84 H20    -     -     - 
  3.05 H21    -     -    2.1    - 
  4.33 H27    -    2.5    -     -     - 
  2.49 H28    -    0.9    -   10.3    -    4.7
  2.57 H29    -    0.7    -    6.5    -     -  -14.5
  2.62 H30   1.7  10.6    -     -     -     -     -     - 
  2.06 H31  10.9   2.1    -     -     -     -     -     -  -13.7
  4.57 H32    -     -     -    5.6    -    0.8    -     -     -     - 
  4.44 H33    -     -    3.6    -     -     -     -     -     -     -     - 
  1.85 H34    -     -     -     -    9.0    -     -     -     -     -   12.9    - 
  2.65 H35    -     -     -     -    0.9    -     -     -     -     -    3.1   0.8 -14.8
  1.09 H36    -     -     -     -     -     -     -     -     -     -     -    7.1    -     - 
  1.09 H37    -     -     -     -     -     -     -     -     -     -     -    7.1    -     -     - 
  1.09 H38    -     -     -     -     -     -     -     -     -     -     -    7.1    -     -     -     - 
  4.60 H39   3.9    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  2.55 H40    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -   -2.7

13C-1H Js
 -ppm- -#-   H10   H17   H18   H20   H21   H27   H28   H29   H30   H31   H32   H33   H34   H35   H36   H37   H38   H39   H40   
 79.18 C2    2.7 144.0   0.7   2.3    -    2.6   0.8   5.8  -6.3  -0.9    -     -     -     -     -     -     -     -     - 
 63.05 C3     -    4.4    -     -     -  158.2  -1.1  -5.0   3.1   1.2    -     -     -     -     -     -     -     -     - 
 38.91 C4     -    1.0    -   -1.9    -   -0.8 127.5 144.2    -     -    5.5    -     -     -     -     -     -     -     - 
 78.08 C5     -     -     -  155.9    -    6.6  -4.7  -1.0    -    0.6  -3.2    -    3.0   6.7    -     -     -     -     - 
 30.77 C6   -2.8  -3.1    -     -     -     -     -    0.7 133.9 129.9    -     -     -     -     -     -     -    4.8    - 
 49.97 C7     -     -     -     -    1.6    -    6.2   1.3    -     -  150.6    -   -5.1  -6.0    -     -     -     -     - 
 71.76 C8  153.0   2.6    -     -     -     -     -     -   -1.0  -6.2    -    6.6    -     -     -     -     -   -4.6  -1.0
 73.07 C11   4.9    -    3.2    -    1.6    -     -     -     -     -     -  147.9    -     -   -3.8  -3.8  -3.8    -     - 
 60.79 C12    -     -  170.6    -   -1.5    -     -     -     -     -     -   -4.6   5.2   6.7   4.0   4.0   4.0    -     - 
 53.63 C13    -     -   -1.4    -  175.7    -     -     -     -     -    3.4   7.6  -5.3  -7.4    -     -     -     -     - 
 35.70 C15    -     -    2.1   5.2   5.0    -     -     -     -     -   -2.2    -  131.3 133.7    -     -     -     -     - 
  8.07 C22    -     -    4.5    -     -     -     -     -     -     -     -   -3.2    -     -  129.2 129.2 129.2    -     - 
 41.31 C23  -2.5    -     -     -     -     -     -     -    1.1   3.1    -     -     -     -     -     -     -  159.8   4.0
 79.41 C24   7.9    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -   -9.0  50.5
 81.79 C25   1.0    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -    2.1 253.0
 -ppm- -#-   H10   H17   H18   H20   H21   H27   H28   H29   H30   H31   H32   H33   H34   H35   H36   H37   H38   H39   H40   
1H data (JH-H abs sorted)

4.84 (10.3, 6.5, 5.6)
4.60 (3.9, 2.7)
4.57 (12.9, 5.6, 3.1, 0.8)
4.44 (7.1, 7.1, 3.6, 0.8)
4.33 (10.6, 2.5, 0.9, 0.7)
4.33 (4.7, 2.5, 0.8)
4.07 (10.9, 3.9, 1.7)
3.05 (9.0, 2.1, 0.9)
2.88 (3.6, 2.1)
2.65 (14.8, 3.1, 0.9, 0.8)
2.62 (13.7, 10.6, 1.7)
2.57 (14.5, 6.5, 0.7)
2.55 (2.7)
2.49 (14.5, 10.3, 4.7, 0.9)
2.06 (13.7, 10.9, 2.1)
1.85 (14.8, 12.9, 9.0)
1.09 (7.1)
13C data
 25  81.8 (253.0, 2.1, 1.0)
 24  79.4 (50.5, -9.0, 7.9)
  2  79.2 (144.0, -6.3, 5.8, 2.7)
  5  78.1 (155.9, 6.7, 6.6, -4.7)
 11  73.1 (147.9, 4.9, -3.8, -3.8)
  8  71.8 (153.0, 6.6, -6.2, -4.6)
  3  63.0 (158.2, -5.0, 4.4, 3.1)
 12  60.8 (170.6, 6.7, 5.2, -4.6)
 13  53.6 (175.7, 7.6, -7.4, -5.3)
  7  50.0 (150.6, 6.2, -6.0, -5.1)
 23  41.3 (159.8, 4.0, 3.1, -2.5)
  4  38.9 (144.2, 127.5, 5.5, -1.9)
 15  35.7 (133.7, 131.3, 5.2, 5.0)
  6  30.8 (133.9, 129.9, 4.8, -3.1)
 22   8.1 (129.2, 129.2, 129.2, 4.5)