(-)-pericosine D - revised (0.22Hz/5)


Gaussian numbering
1H-1H Js
 -ppm- -#-   H9    H10   H11   H14   H15   H18   H20   H22   H23   H24   H25   
  3.82 H9 
  3.82 H10    - 
  3.82 H11    -     - 
  7.24 H14    -     -     - 
  4.55 H15    -     -     -    2.8
  3.98 H18    -     -     -     -    8.2
  4.29 H20    -     -     -     -     -    2.8
  4.88 H22    -     -     -     -    1.2    -    2.5
  2.21 H23    -     -     -     -     -     -     -     - 
  1.15 H24    -     -     -     -     -    1.0   1.2    -     - 
  1.87 H25    -     -     -     -     -    6.2    -     -     -     - 

13C-1H Js
 -ppm- -#-   H9    H10   H11   H14   H15   H18   H20   H22   H23   H24   H25   
165.72 C1    4.1   4.1   4.1   6.4  -1.6    -    0.9   2.7    -     -     - 
129.13 C2     -     -     -   -2.2   6.0    -    5.7  -5.6    -     -     - 
 50.46 C5  147.1 147.1 147.1    -     -     -     -     -     -     -     - 
147.55 C6     -     -     -  170.6  -7.8   1.2    -    5.2    -     -     - 
 69.93 C7     -     -     -     -  142.3  -4.5   4.5  -0.7    -     -     - 
 69.55 C8     -     -     -    5.8  -5.4 151.2  -4.1   5.0    -     -     - 
 74.74 C12    -     -     -     -    0.9    -  155.2  -3.7    -     -     - 
 55.22 C13    -     -     -    9.7  -0.6   0.7  -1.6 157.4    -     -     - 
 -ppm- -#-   H9    H10   H11   H14   H15   H18   H20   H22   H23   H24   H25   
1H data (JH-H abs sorted)

7.24 (2.8)
4.88 (2.5, 1.2)
4.55 (8.2, 2.8, 1.2)
4.29 (2.8, 2.5, 1.2)
3.98 (8.2, 6.2, 2.8, 1.0)
3.82
2.21
1.87 (6.2)
1.15 (1.2, 1.0)
13C data
  1 165.7 (6.4, 4.1, 4.1, 4.1)
  6 147.5 (170.6, -7.8, 5.2, 1.2)
  2 129.1 (6.0, 5.7, -5.6, -2.2)
 12  74.7 (155.2, -3.7, 0.9)
  7  69.9 (142.3, 4.5, -4.5, -0.7)
  8  69.5 (151.2, 5.8, -5.4, 5.0)
 13  55.2 (157.4, 9.7, -1.6, 0.7)
  5  50.5 (147.1, 147.1, 147.1)