picrinine (0.19Hz/13)


FRACTIONS (manually entered): 0.273 0.727 (major structure is shown)
Rel. DFT Energies (kcal/mol): 1.789 0.000
Gaussian numbering
1H-1H Js
 -ppm- -#-   H3    H4    H5    H12   H13   H14   H15   H22   H24   H25   H26   H27   H28   H30   H36   H37   H38   H41   H42   H45   H46   H47   
  4.25 H3 
  3.51 H4     - 
  2.36 H5     -  -13.8
  7.17 H12    -     -     - 
  6.76 H13    -     -     -    7.5
  7.06 H14    -     -     -    1.3   7.3
  6.75 H15    -     -     -    0.6   1.1   7.8
  2.62 H22    -     -    0.7    -     -     -     - 
  3.46 H24    -     -     -     -     -     -     -    3.8
  2.05 H25    -     -     -     -     -     -     -     -    3.2
  1.93 H26    -     -     -     -     -     -     -     -    3.2 -14.0
  5.59 H27    -     -     -     -     -     -     -     -   -1.4    -    0.6
  3.49 H28    -     -     -     -     -     -     -     -    1.0   5.0   1.3    - 
  4.58 H30    -     -    2.4    -     -     -     -    0.7    -     -    0.9    -     - 
  3.66 H36    -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  3.66 H37    -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  3.66 H38    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  3.17 H41    -     -     -     -     -     -     -     -     -     -     -   -1.0    -     -     -     -     - 
  3.98 H42    -     -     -     -     -     -     -     -   -0.6    -     -   -2.4   0.8    -     -     -     -  -17.6
  1.66 H45    -     -     -     -     -     -     -     -    0.9    -     -    7.3    -     -     -     -     -    1.0   2.7
  1.66 H46    -     -     -     -     -     -     -     -    0.9    -     -    7.3    -     -     -     -     -    1.0   2.7    - 
  1.66 H47    -     -     -     -     -     -     -     -    0.9    -     -    7.3    -     -     -     -     -    1.0   2.7    -     - 

13C-1H Js
 -ppm- -#-   H3    H4    H5    H12   H13   H14   H15   H22   H24   H25   H26   H27   H28   H30   H36   H37   H38   H41   H42   H45   H46   H47   
149.49 C2     -     -     -    8.5  -1.5   8.9  -0.9    -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
136.55 C6     -    2.2   5.8    -    8.0  -1.5   5.5   2.3    -     -     -     -     -     -     -     -     -     -     -     -     -     - 
126.39 C7     -     -     -  162.8   2.1   8.1  -1.3    -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
120.43 C8     -     -     -    1.1 161.9   1.2   6.9    -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
128.43 C9     -     -     -    7.7   2.0 160.2    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
110.46 C10    -     -     -   -1.4   8.2   1.5 159.6    -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
 54.03 C11    -   -2.7  -4.5   2.9    -     -     -   -3.7   6.1    -     -     -    3.8   5.3    -     -     -     -     -     -     -     - 
 54.31 C16    -    3.6   3.0    -     -     -     -  132.2  -4.2   9.0   2.4  -1.0    -     -     -     -     -     -   -1.1   0.9   0.9   0.9
 34.11 C17    -     -     -     -     -     -     -   -5.0 137.9  -2.6  -3.4   8.5   5.8    -     -     -     -    3.6   1.3  -0.8  -0.8  -0.8
 26.53 C18    -     -     -     -     -     -     -    2.9  -3.9 132.1 131.8    -   -0.7    -     -     -     -     -     -     -     -     - 
 53.27 C19    -     -     -     -     -     -     -     -    6.0  -4.3  -2.7    -  150.4   4.4    -     -     -    7.2    -     -     -     - 
104.87 C20    -    2.8   0.8    -     -     -     -    1.0    -    9.1   2.3    -   -4.7   7.9    -     -     -     -     -     -     -     - 
 42.87 C21    -  139.2 136.8    -     -     -     -    5.6    -     -     -     -     -    5.9    -     -     -     -   -0.7    -     -     - 
175.31 C23    -     -     -     -     -     -     -   -7.3   2.2   1.5    -     -     -     -    4.0   4.0   4.0    -     -     -     -     - 
 86.93 C29    -   -1.4  -3.7    -     -     -     -     -     -     -     -     -    1.3 170.0    -     -     -    3.5  10.2    -     -     - 
 49.85 C35    -     -     -     -     -     -     -     -     -     -     -     -     -     -  146.9 146.9 146.9    -     -     -     -     - 
 13.03 C39    -     -     -     -     -     -     -     -     -     -     -    2.7    -     -     -     -     -   -0.6  -1.3 128.2 128.2 128.2
 46.98 C40    -     -    0.7    -     -     -     -     -    3.9    -     -    7.2   2.0    -     -     -     -  136.2 139.9  -0.9  -0.9  -0.9
142.69 C43    -     -     -     -     -     -     -    6.1  -5.5   1.8   5.9  -1.2    -     -     -     -     -   -4.0  -6.1   5.8   5.8   5.8
123.39 C44    -     -     -     -     -     -     -     -    4.2    -    0.7 151.5    -     -     -     -     -    4.3   5.1  -7.0  -7.0  -7.0
 -ppm- -#-   H3    H4    H5    H12   H13   H14   H15   H22   H24   H25   H26   H27   H28   H30   H36   H37   H38   H41   H42   H45   H46   H47   
1H data (JH-H abs sorted)

7.17 (7.5, 1.3, 0.6)
7.06 (7.8, 7.3, 1.3)
6.76 (7.5, 7.3, 1.1)
6.75 (7.8, 1.1, 0.6)
5.59 (2.4, 1.4, 1.0, 0.6)
4.58 (2.4, 0.9, 0.7)
4.25
3.98 (17.6, 2.4, 0.8, 0.6)
3.66
3.51 (13.8)
3.49 (5.0, 1.3, 1.0, 0.8)
3.46 (3.8, 3.2, 3.2, 1.4)
3.17 (17.6, 1.0, 1.0, 1.0)
2.62 (3.8, 0.7, 0.7)
2.36 (13.8, 2.4, 0.7)
2.05 (14.0, 5.0, 3.2)
1.93 (14.0, 3.2, 1.3, 0.6)
1.66 (7.3, 2.7, 1.0, 0.9)
13C data
 23 175.3 (-7.3, 4.0, 4.0, 4.0)
  2 149.5 (8.9, 8.5, -1.5, -0.9)
 43 142.7 (6.1, -6.1, 5.9, 5.8)
  6 136.6 (8.0, 5.8, 5.5, 2.3)
  9 128.4 (160.2, 7.7, 2.0)
  7 126.4 (162.8, 8.1, 2.1, -1.3)
 44 123.4 (151.5, -7.0, -7.0, -7.0)
  8 120.4 (161.9, 6.9, 1.2, 1.1)
 10 110.5 (159.6, 8.2, 1.5, -1.4)
 20 104.9 (9.1, 7.9, -4.7, 2.8)
 29  86.9 (170.0, 10.2, -3.7, 3.5)
 16  54.3 (132.2, 9.0, -4.2, 3.6)
 11  54.0 (6.1, 5.3, -4.5, 3.8)
 19  53.3 (150.4, 7.2, 6.0, 4.4)
 35  49.9 (146.9, 146.9, 146.9)
 40  47.0 (139.9, 136.2, 7.2, 3.9)
 21  42.9 (139.2, 136.8, 5.9, 5.6)
 17  34.1 (137.9, 8.5, 5.8, -5.0)
 18  26.5 (132.1, 131.8, -3.9, 2.9)
 39  13.0 (128.2, 128.2, 128.2, 2.7)