protoilludanes alkene 13 (0.38Hz/12)


Gaussian numbering
1H-1H Js
 -ppm- -#-   H3    H4    H5    H11   H14   H16   H17   H18   H20   H21   H24   H26   H27   H28   H30   H31   H32   H33   H34   H35   
  1.60 H3 
  1.27 H4     - 
  1.37 H5  -12.7    - 
  2.40 H11   7.7    -   12.3
  3.38 H14    -     -     -     - 
  5.92 H16    -     -     -    0.9  -1.9
  5.71 H17    -     -     -    0.7   5.6   9.8
  2.83 H18   0.7    -     -    6.6   2.9   2.4  -2.8
  2.01 H20    -     -     -     -     -     -     -    7.8
  1.74 H21    -     -     -     -     -     -     -    0.8 -12.9
  1.27 H24    -     -     -     -     -     -     -     -     -     - 
  1.27 H26    -     -     -     -     -     -     -     -     -     -     - 
  2.59 H27    -     -     -     -    5.8    -     -     -     -     -     -     - 
  3.06 H28    -    0.9    -     -   -2.8    -     -     -     -     -    0.9   0.9 -16.9
  1.16 H30    -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  1.16 H31    -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  1.16 H32    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  1.15 H33    -     -     -     -     -     -     -     -    0.7    -     -     -     -     -     -     -     - 
  1.15 H34    -     -     -     -     -     -     -     -    0.7    -     -     -     -     -     -     -     -     - 
  1.15 H35    -     -     -     -     -     -     -     -    0.7    -     -     -     -     -     -     -     -     -     - 

13C-1H Js
 -ppm- -#-   H3    H4    H5    H11   H14   H16   H17   H18   H20   H21   H24   H26   H27   H28   H30   H31   H32   H33   H34   H35   
 42.38 C1  130.9    -  127.6  -3.9    -     -     -    5.5    -    3.8    -     -     -     -    4.8   4.8   4.8   4.7   4.7   4.7
 44.24 C2   -3.0   3.7  -4.2 127.8   1.8   5.0    -   -3.5    -    6.9   3.7   3.7   1.3   4.5    -     -     -     -     -     - 
 31.36 C6    0.6  -3.9   3.9  -3.7  -2.2    -    6.4   1.2    -    0.7  -3.9  -3.9  -2.1  -3.9    -     -     -     -     -     - 
 63.24 C7     -    5.1    -    5.3 141.0   8.4   2.7  -1.4    -     -    5.1   5.1   6.8    -     -     -     -     -     -     - 
123.54 C8     -     -     -     -   -7.2   0.7 162.8   6.1   0.7    -     -     -   -0.8    -     -     -     -     -     -     - 
134.75 C9     -     -     -    5.7   6.4 158.9  -0.6  -7.3   8.2   5.8    -     -     -     -     -     -     -     -     -     - 
 41.45 C10   7.5    -    0.6  -3.6  -1.0   3.3   7.8 130.5  -3.5  -3.0    -     -     -     -     -     -     -     -     -     - 
 54.76 C12    -    5.3    -    2.5   5.5    -     -     -     -     -    5.3   5.3 137.8 132.0    -     -     -     -     -     - 
 24.09 C13    -  127.0    -    1.9   4.6    -     -     -     -     -  127.0 127.0   5.4   5.4    -     -     -     -     -     - 
203.44 C15    -     -     -   -0.7  -6.7  -1.6   2.5   2.9    -     -     -     -   -5.5  -6.5    -     -     -     -     -     - 
 47.46 C19   3.6    -    0.8   0.8   1.1   3.6  -0.6  -4.1 127.1 130.9    -     -     -     -    4.8   4.8   4.8   4.6   4.6   4.6
 39.83 C22  -2.4    -   -3.7   0.6    -     -     -    6.8  -3.5  -2.5    -     -     -     -   -3.6  -3.6  -3.6  -3.6  -3.6  -3.6
 30.28 C23   1.4    -    6.7    -     -     -     -     -    4.9   5.5    -     -     -     -    4.7   4.7   4.7 126.3 126.3 126.3
 30.32 C25   5.8    -    4.6    -     -     -     -     -    6.9   1.3    -     -     -     -  125.9 125.9 125.9   4.9   4.9   4.9
 -ppm- -#-   H3    H4    H5    H11   H14   H16   H17   H18   H20   H21   H24   H26   H27   H28   H30   H31   H32   H33   H34   H35   
1H data (JH-H abs sorted)

5.92 (9.8, 2.4, 1.9, 0.9)
5.71 (9.8, 5.6, 2.8, 0.7)
3.38 (5.8, 5.6, 2.9, 1.9)
3.06 (2.8, 0.9, 0.9, 0.9)
2.83 (6.6, 2.9, 2.4, 0.7)
2.59 (16.9, 5.8)
2.40 (12.3, 7.7, 0.9, 0.7)
2.01 (12.9, 7.8, 0.7, 0.7)
1.74 (12.9, 0.8)
1.60 (12.7, 7.7, 0.7)
1.37 (12.7, 12.3)
1.27 (0.9)
1.16
1.15 (0.7)
13C data
 15 203.4 (-6.7, -6.5, -5.5, 2.9)
  9 134.8 (158.9, 8.2, -7.3, 6.4)
  8 123.5 (162.8, -7.2, 6.1, -0.8)
  7  63.2 (141.0, 8.4, 6.8, 5.3)
 12  54.8 (137.8, 132.0, 5.5, 5.3)
 19  47.5 (130.9, 127.1, 4.8, 4.8)
  2  44.2 (127.8, 6.9, 5.0, 4.5)
  1  42.4 (130.9, 127.6, 5.5, 4.8)
 10  41.5 (130.5, 7.8, 7.5, -3.6)
 22  39.8 (6.8, -3.7, -3.6, -3.6)
  6  31.4 (6.4, -3.9, 3.9, -3.9)
 25  30.3 (125.9, 125.9, 125.9, 6.9)
 23  30.3 (126.3, 126.3, 126.3, 6.7)
 13  24.1 (127.0, 127.0, 127.0, 5.4)