FRACTIONS (manually entered): 0.115 0.885 (major structure is shown)
Rel. DFT Energies (kcal/mol): 3.488 0.000

Gaussian numbering

¹H-¹H Js
 -ppm- -#-   H3    H4    H5    H11   H14   H16   H17   H19   H21   H22   H25   H27   H28   H29   H31   H32   H33   H34   H35   H36   
  1.60 H3 
  1.19 H4     - 
  1.33 H5  -12.9    - 
  2.29 H11   6.8    -   11.7
  2.93 H14    -     -     -     - 
  3.30 H16    -     -     -     -    5.4
  2.89 H17    -     -     -    0.7    -    3.2
  2.58 H19   1.1    -     -    6.4    -    0.8   1.0
  2.01 H21    -     -     -     -     -     -     -    8.2
  1.71 H22    -     -     -     -     -     -     -    2.4 -13.6
  1.19 H25    -     -     -     -     -     -     -     -     -     - 
  1.19 H27    -     -     -     -     -     -     -     -     -     -     - 
  2.46 H28    -     -     -     -    6.2    -     -     -     -     -     -     - 
  3.11 H29    -    1.1    -     -   -2.0    -     -     -     -     -    1.1   1.1 -16.1
  1.17 H31    -     -    0.7    -     -     -     -     -     -     -     -     -     -     - 
  1.17 H32    -     -    0.7    -     -     -     -     -     -     -     -     -     -     -     - 
  1.17 H33    -     -    0.7    -     -     -     -     -     -     -     -     -     -     -     -     - 
  1.15 H34    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  1.15 H35    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  1.15 H36    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 

¹³C-¹H Js
 -ppm- -#-   H3    H4    H5    H11   H14   H16   H17   H19   H21   H22   H25   H27   H28   H29   H31   H32   H33   H34   H35   H36   
 43.27 C1  131.4    -  125.8  -3.9    -     -     -    5.9   1.6   2.4    -     -     -     -    4.7   4.7   4.7   4.7   4.7   4.7
 43.77 C2   -2.8   3.7  -4.0 128.8   1.1    -    3.5  -3.3   1.4   5.5   3.7   3.7   1.0   4.3    -     -     -     -     -     - 
 30.57 C6    1.3  -3.8   3.7  -3.7  -2.3   5.1    -    1.6    -    0.7  -3.8  -3.8  -1.8  -4.4    -     -     -     -     -     - 
 59.94 C7     -    5.1    -    5.3 139.5   4.8   0.8    -     -     -    5.1   5.1   7.0    -     -     -     -     -     -     - 
 51.14 C8     -     -     -     -   -1.9 177.3  -0.7   4.3    -     -     -     -   -0.8    -     -     -     -     -     -     - 
 54.89 C9     -     -     -    5.5    -   -0.9 173.2  -6.7  10.8   7.7    -     -     -     -     -     -     -     -     -     - 
 40.24 C10   7.2    -    1.3  -3.7    -    0.7   5.4 133.8  -3.2  -3.4    -     -     -     -     -     -     -     -     -     - 
 57.63 C12    -    5.1    -    2.7   5.9    -     -     -     -     -    5.1   5.1 138.3 134.6    -     -     -     -     -     - 
 25.23 C13    -  127.4    -    1.8   5.0    -     -     -     -     -  127.4 127.4   5.5   6.5    -     -     -     -     -     - 
203.72 C15    -     -     -   -0.6  -5.8    -     -     -     -     -     -     -   -5.4  -6.9    -     -     -     -     -     - 
 45.77 C20   4.8    -     -    1.5    -     -    3.4  -3.5 128.8 129.5    -     -     -     -    4.8   4.8   4.8   4.7   4.7   4.7
 38.53 C23  -2.5    -   -3.6   1.4    -     -     -    6.1  -3.5  -2.7    -     -     -     -   -3.5  -3.5  -3.5  -3.6  -3.6  -3.6
 29.30 C24   1.1    -    6.3    -     -     -     -     -    3.7   5.9    -     -     -     -    4.8   4.8   4.8 126.0 126.0 126.0
 30.05 C26   5.4    -    5.1    -     -     -     -     -    6.8   2.4    -     -     -     -  126.2 126.2 126.2   4.7   4.7   4.7
 -ppm- -#-   H3    H4    H5    H11   H14   H16   H17   H19   H21   H22   H25   H27   H28   H29   H31   H32   H33   H34   H35   H36

¹H data (J_H-H abs sorted)

3.30 (5.4, 3.2, 0.8)
3.11 (2.0, 1.1, 1.1, 1.1)
2.93 (6.2, 5.4, 2.0)
2.89 (3.2, 1.0, 0.7)
2.58 (6.4, 1.1, 1.0, 0.8)
2.46 (16.1, 6.2)
2.29 (11.7, 6.8, 6.4, 0.7)
2.01 (13.6, 8.2)
1.71 (13.6, 2.4)
1.60 (12.9, 6.8, 1.1)
1.33 (12.9, 11.7, 0.7, 0.7)
1.19 (1.1)
1.17 (0.7)
1.15

¹³C data

 15 203.7 (-6.9, -5.8, -5.4, -0.6)
  7  59.9 (139.5, 7.0, 5.3, 5.1)
 12  57.6 (138.3, 134.6, 5.9, 5.1)
  9  54.9 (173.2, 10.8, 7.7, -6.7)
  8  51.1 (177.3, 4.3, -1.9, -0.8)
 20  45.8 (129.5, 128.8, 4.8, 4.8)
  2  43.8 (128.8, 5.5, 4.3, -4.0)
  1  43.3 (131.4, 125.8, 5.9, 4.7)
 10  40.2 (133.8, 7.2, 5.4, -3.7)
 23  38.5 (6.1, -3.6, -3.6, -3.6)
  6  30.6 (5.1, -4.4, -3.8, -3.8)
 26  30.1 (126.2, 126.2, 126.2, 6.8)
 24  29.3 (126.0, 126.0, 126.0, 6.3)
 13  25.2 (127.4, 127.4, 127.4, 6.5)

protoilludanes epoxide 15 (0.29Hz/10)