(+)-strictamine (0.33Hz/13)


FRACTIONS (manually entered): 0.174 0.826 (major structure is shown)
Rel. DFT Energies (kcal/mol): 1.686 0.000
Gaussian numbering
1H-1H Js
 -ppm- -#-   H3    H4    H11   H12   H13   H14   H21   H23   H24   H25   H26   H27   H29   H30   H35   H36   H37   H40   H41   H44   H45   H46   
  3.91 H3 
  2.00 H4  -14.8
  7.40 H11    -     - 
  7.08 H12    -     -    7.5
  7.28 H13    -     -    1.3   7.3
  7.54 H14    -     -    0.7   1.1   7.8
  2.09 H21    -    0.8    -     -     -     - 
  3.59 H23    -     -     -     -     -     -    4.1
  2.54 H24    -     -     -     -     -     -     -    2.6
  1.72 H25    -     -     -     -     -     -     -    3.4 -13.8
  5.61 H26    -     -     -     -     -     -     -   -1.6    -    0.6
  4.64 H27    -     -     -     -     -     -     -     -    5.5   1.3    - 
  2.75 H29  14.7   5.3    -     -     -     -     -     -     -     -     -     - 
  2.71 H30   6.1   0.7    -     -     -     -     -     -     -    0.9    -     -  -14.1
  3.74 H35    -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  3.74 H36    -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  3.74 H37    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
  3.22 H40    -     -     -     -     -     -     -     -     -     -   -0.8    -     -     -     -     -     - 
  4.34 H41    -     -     -     -     -     -     -   -0.9    -    0.7  -2.4   0.7    -     -     -     -     -  -16.8
  1.81 H44    -     -     -     -     -     -     -    1.0    -     -    7.3    -     -     -     -     -     -    0.8   2.7
  1.81 H45    -     -     -     -     -     -     -    1.0    -     -    7.3    -     -     -     -     -     -    0.8   2.7    - 
  1.81 H46    -     -     -     -     -     -     -    1.0    -     -    7.3    -     -     -     -     -     -    0.8   2.7    -     - 

13C-1H Js
 -ppm- -#-   H3    H4    H11   H12   H13   H14   H21   H23   H24   H25   H26   H27   H29   H30   H35   H36   H37   H40   H41   H44   H45   H46   
158.36 C2     -     -    7.9  -1.6   8.7  -1.8    -     -     -     -     -   -0.7    -     -     -     -     -     -     -     -     -     - 
147.91 C5    1.6   5.5    -    8.2  -1.5   5.5   2.3    -     -     -     -    0.7    -     -     -     -     -     -     -     -     -     - 
123.72 C6     -     -  163.9   2.0   8.2  -1.4    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
124.65 C7     -     -    1.3 160.9   1.5   7.4    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
128.33 C8     -     -    7.6   1.7 160.9   0.9    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
121.96 C9     -     -   -1.5   7.9   1.3 164.1    -     -     -     -     -     -     -     -     -     -     -     -     -     -     -     - 
 57.82 C10  -4.3  -4.1   2.3   0.6    -     -   -3.0   6.4    -     -     -    3.2   1.2   8.0    -     -     -     -     -     -     -     - 
 57.06 C15   5.8   3.3    -     -     -     -  132.1  -3.9  10.6   2.1  -1.1    -     -     -     -     -     -     -   -1.2   0.9   0.9   0.9
 35.26 C16    -     -     -     -     -     -   -5.1 137.4  -2.3  -3.2   8.7   5.5    -     -     -     -     -    4.1   1.3  -0.8  -0.8  -0.8
 36.84 C17    -     -     -     -     -     -    2.6  -3.7 133.6 133.8    -   -2.3    -     -     -     -     -    0.8    -     -     -     - 
 56.06 C18    -     -     -     -     -     -     -    6.1  -4.0  -1.5    -  155.2   1.4   7.7    -     -     -    7.0   0.7    -     -     - 
193.79 C19   3.4   0.7    -     -     -   -0.8   1.2    -    6.7   2.1    -   -4.5    -     -     -     -     -     -     -     -     -     - 
 36.44 C20 137.7 132.5    -     -     -     -    5.4    -     -     -     -    0.8  -1.5    -     -     -     -     -     -     -     -     - 
174.68 C22    -     -     -     -     -     -   -7.3   1.8   1.6    -     -     -     -     -    4.1   4.1   4.1    -     -     -     -     - 
 50.82 C28  -4.1  -2.5    -     -     -     -     -     -     -     -     -    1.2 137.7 138.0    -     -     -    3.1   9.0    -     -     - 
 49.93 C34    -     -     -     -     -     -     -     -     -     -     -     -     -     -  147.1 147.1 147.1    -     -     -     -     - 
 13.20 C38    -     -     -     -     -     -     -     -     -     -    2.7    -     -     -     -     -     -     -   -1.2 128.2 128.2 128.2
 54.54 C39    -     -     -     -     -     -     -    3.7    -     -    7.1   1.9   9.2   2.4    -     -     -  137.8 138.0  -0.9  -0.9  -0.9
144.81 C42    -     -     -     -     -     -    6.1  -5.7   2.0   6.2  -0.9    -     -     -     -     -     -   -3.4  -6.1   5.8   5.8   5.8
122.67 C43    -     -     -     -     -     -     -    4.2    -    0.7 152.5    -     -     -     -     -     -    4.2   5.2  -7.0  -7.0  -7.0
 -ppm- -#-   H3    H4    H11   H12   H13   H14   H21   H23   H24   H25   H26   H27   H29   H30   H35   H36   H37   H40   H41   H44   H45   H46   
1H data (JH-H abs sorted)

7.54 (7.8, 1.1, 0.7)
7.40 (7.5, 1.3, 0.7)
7.28 (7.8, 7.3, 1.3)
7.08 (7.5, 7.3, 1.1)
5.61 (2.4, 1.6, 0.8, 0.6)
4.64 (5.5, 1.3, 0.7)
4.34 (2.4, 0.9, 0.7, 0.7)
3.91 (14.8, 14.7, 6.1)
3.74
3.59 (4.1, 3.4, 2.6, 1.6)
3.22 (16.8, 0.8, 0.8, 0.8)
2.75 (14.7, 14.1, 5.3)
2.71 (14.1, 6.1, 0.9, 0.7)
2.54 (13.8, 5.5, 2.6)
2.09 (4.1, 0.8)
2.00 (14.8, 5.3, 0.8, 0.7)
1.81 (7.3, 2.7, 1.0, 0.8)
1.72 (13.8, 3.4, 1.3, 0.6)
13C data
 19 193.8 (6.7, -4.5, 3.4, 2.1)
 22 174.7 (-7.3, 4.1, 4.1, 4.1)
  2 158.4 (8.7, 7.9, -1.8, -1.6)
  5 147.9 (8.2, 5.5, 5.5, 2.3)
 42 144.8 (6.2, 6.1, -6.1, 5.8)
  8 128.3 (160.9, 7.6, 1.7, 0.9)
  7 124.6 (160.9, 7.4, 1.5, 1.3)
  6 123.7 (163.9, 8.2, 2.0, -1.4)
 43 122.7 (152.5, -7.0, -7.0, -7.0)
  9 122.0 (164.1, 7.9, -1.5, 1.3)
 10  57.8 (8.0, 6.4, -4.3, -4.1)
 15  57.1 (132.1, 10.6, 5.8, -3.9)
 18  56.1 (155.2, 7.7, 7.0, 6.1)
 39  54.5 (138.0, 137.8, 9.2, 7.1)
 28  50.8 (138.0, 137.7, 9.0, -4.1)
 34  49.9 (147.1, 147.1, 147.1)
 17  36.8 (133.8, 133.6, -3.7, 2.6)
 20  36.4 (137.7, 132.5, 5.4, -1.5)
 16  35.3 (137.4, 8.7, 5.5, -5.1)
 38  13.2 (128.2, 128.2, 128.2, 2.7)