Addressing the Challenges of Structure Elucidation in Natural Products Possessing the Oxirane Moiety. Kutateladze, A.G.; Kuznetsov, D.M.; Beloglazkina, A. A.; Holt, T. J. Org. Chem., 2018, 83, (15), 8341-8352. [DOI: 10.1021/acs.joc.8b01027] Featured Article. ACS Editors' Choice (made 20 most read JOC articles in August 2018)
Step-Economical Photoassisted Diversity-Oriented Synthesis: Sustaining Cascade Photoreactions in Oxalyl Anilides to Access Complex Polyheterocyclic Molecular Architectures. Kuznetsov, D.M.; Kutateladze, A.G. J. Am. Chem. Soc., 2017, 139, (46), 16584-16590. [DOI: 10.1021/jacs.7b07598]
Triquinanes and Related Sesquiterpenes Revisited Computationally: Structure Corrections of Hirsutanols B and D, Hirsutenol E, Cucumin B, Antrodins C−E, Chondroterpenes A and H, Chondrosterins C and E, Dichrocephone A, and Pethybrene. Kutateladze, A.G.; Kuznetsov, D.M. J. Org. Chem., 2017, 82, (20), 10795-10802. [DOI: 10.1021/acs.joc.7b02018] Featured Article. ACS Editors' Choice.
Photoassisted Synthesis of Complex Molecular Architectures: Dearomatization of Benzenoid Arenes with Aza-o-xylylenes via an Unprecedented [2+4] Reaction Topology. Kuznetsov, D.M.; Mukhina, O.A.; Kutateladze, A.G. Angew. Chem., 2016, 55, (24), 6988-6991. [DOI: 10.1002/anie.201602288]
Intramolecular Cycloadditions of Photogenerated Azaxylylenes with Oxadiazoles Provide Direct Access to Versatile Polyheterocyclic Ketopiperazines Containing a Spiro-Oxirane Moiety. Kumar, N.N.B.; Kuznetsov, D.M.; Kutateladze, A.G. Org. Lett. , 2015, 17, (3), 438-441. [DOI: 10.1021/ol5033909]
Maximizing Step-Normalized Increases in Molecular Complexity: Formal [4+2+2+2] Photoinduced Cyclization Cascade to Access Polyheterocycles Possessing Privileged Substructures. Reddy, D.S.; Novitskiy, I.M.; Kutateladze, A.G. Angew. Chem. Int. Ed., 2022, 61, (4), e202112573. [DOI: 10.1002/anie.202112573] Angewandte's Hot Paper
The Discreet Structural Diversity of Briarellins: DU8+ Guided Multiple Structure Revisions Yielded Two Unknown Structural Types. Holt, T. A.; Reddy, D. S.; Huple, D. B.; West, L. M.; Rodriguez, A. D.; Crimmins, M. T.; Kutateladze, A. G. J. Org. Chem., 2020, 85, (9), 6201-6205. [DOI: 10.1021/acs.joc.0c00555]
Photoinitiated Cascade for Rapid Access to Pyrroloquinazolinone Core of Vasicinone, Luotonins, and Related Alkaloids. Reddy, D. S.; Kutateladze, A. G. Org. Lett., 2019, 21, (8), 2855-2858.. [DOI: 10.1021/acs.orglett.9b00858]
Natural Products Containing the Oxetane and Related Moieties Present Additional Challenge for Structure Elucidation: a DU8+ Computational Case Study. Kutateladze, A. G.; Holt, T. A.; Reddy, D. S. J. Org. Chem., 2019, 84, (12), 7575-7586. [DOI: 10.1021/acs.joc.9b01005] Featured Article
High-Throughput in Silico Structure Validation and Revision of Halogenated Natural Products Is Enabled by Parametric Corrections to DFT-Computed 13C NMR Chemical Shifts and Spin-Spin Coupling Constants. Kutateladze, A.G.; Reddy, D.S. J. Org. Chem., 2017, 82, (7), 3368-3381. [DOI: 10.1021/acs.joc.7b00188]
Polyheterocycle-carbohydrate chimeras: photoassisted synthesis of 2,5-epoxybenzoxacines and 2,5-epoxybenzazocine scaffolds and their postphotochemical hydroxylations. Reddy, D.S.; Mukhina, O.A.; Cronk, W.C.; Kutateladze, A.G. Pure Applied Chem., 2017, 89, (2), 259-268. [DOI: 10.1515/pac-2016-0915]
Structure Revision of an Acorane Sesquiterpene Cordycepol A. Reddy, D.S.; Kutateladze, A.G. Org. Lett., 2016, 18, (19), 4860-4863. [DOI: 10.1021/acs.orglett.6b02341]
Computational structure revision of a longipinane derivative meridane. Reddy, D.S.; Kutateladze, A.G. Tetrahedron Lett., 2016, 57, (42), 4727-4729. [DOI: 10.1016/j.tetlet.2016.09.030]
Systematic Photoassisted Access to Designer Polyheterocycles via Modular Blocks and Scaffolding. Holt. T. A.; Novitskiy, I. M.; Kutateladze, A. G. Org. Lett., 2024, 26, (3), 734-738. [DOI: 10.1021/acs.orglett.3c04186]
seco-Pregnane Glycosides from Australian Caustic Vine (Cynanchum viminale subsp. australe) Xue. Y.; Savchenko A.I.; Agnew-Francis, K.A.; Miles, J.A.; Holt, T.; Lu, H.; Chow, S.; Forster, P.I.; Boyle, G. M.; Ross, B.P.; Fisher, K.; Kutateladze, A.G.; Williams, C.M. J. Nat. Prod. , 2023, 86, 490-497. [DOI: 10.1021/acs.jnatprod.2c01037]
Rearrangements of the Radical Cations of 3-Aryl-5-fluoroisoxazoles: Further Evidence for Existence of Benzocyclopropenyl Cation. Bondarenko, O.B.; Komarov, A.I.; Nikolaeva, S.N.; Holt, T.A.; Kutateladze, A.G.; Gloriozov, I.P. J. Am. Soc. Mass Spectrom., 2023, 34, 2547-2555. [DOI: 10.1021/jasms.3c00267]
Structure revision of ent-kaurane diterpenoids, isoserrins A, B, and D, enabled by DU8+ computation of their NMR spectral data. Novitskiy, I.M.; Holt, T.A.; Kutateladze, A.G. Mendeleev Comm. , 2021, 31, 300-301. [DOI: 10.1016/j.mencom.2021.05.007]
The Discreet Structural Diversity of Briarellins: DU8+ Guided Multiple Structure Revisions Yielded Two Unknown Structural Types. Holt, T. A.; Reddy, D. S.; Huple, D. B.; West, L. M.; Rodriguez, A. D.; Crimmins, M. T.; Kutateladze, A. G. J. Org. Chem., 2020, 85, (9), 6201-6205. [DOI: 10.1021/acs.joc.0c00555]
EBC-232 and 323:A Structural Conundrum Necessitating Unification of Five In Silico Prediction and Elucidation Methods. Maslovskaya, L. A.; Savchenk, A. I.; Krenske, E. H.; Chow, S.; Holt, T.; Gordon, V. A.; Reddell, P. W.; Pierce, C. J.; Parsons, P. G.; Boyle, G. M.; Kutateladze, A. G.; Williams, C. M. Chem. Eur. J., 2020, 26, 11862-11867. [DOI: 10.1002/chem.202001884]
Stereochemical revision of xylogranatin F by GIAO and DU8+ NMR calculations. Liu, Y.; Holt, T. A.; Kutateladze, A. G.; Newhouse, T. R. Chirality, 2020, 32, 515-523. [DOI: 10.1002/chir.23189]
Dichotomy in the reactivity of 2-methyltetrahydroquinazoline 1-oxides towards aldehydes: An unprecedented condensation with simultaneous reduction of the N-oxide fragment. Sedenkova, K. N.;Terekhin, A. V.; Abdrashitova, I. V.; Vasilenko, D. A.; Sadovnikov, K. S.; Gracheva, Y. A.; Grishin, Y. K.; Holt, T. A.; Kutateladze, A. G.; Kuznetsova, T. S.; Milaeva, E. R.; Averina, E. B. Tetrahedron Lett., 2020, 61, (11), 151605. [DOI: 10.1016/j.tetlet.2020.151605]
Natural Products Containing the Oxetane and Related Moieties Present Additional Challenge for Structure Elucidation: a DU8+ Computational Case Study. Kutateladze, A. G.; Holt, T. A.; Reddy, D. S. J. Org. Chem., 2019, 84, (12), 7575-7586. [DOI: 10.1021/acs.joc.9b01005] Featured Article
Structure Validation of Complex Natural Products: Time to Change the Paradigm. What did Synthesis of Alstofolinine A Prove? Kutateladze, A. G.; Holt, T. A. J. Org. Chem., 2019, 84, (12), 8297-8299. [DOI: 10.1021/acs.joc.9b00969]
Diastereoselective heterocyclization of geminal bromo-fluoro arylcyclopropanes by nitrosonium tetrafluoroborate: Access to 4-fluorinated isoxazolines and isoxazoles. Bondarenko, O. B.; Komarov, A. I.; Karetnikov, G. L.; Nikolaeva, S. N.; Zyk, N. V.; Holt, T. A.; Kutateladze, A. G. Tetrahedron, 2019, 75, (46), 130666. [DOI: 10.1016/j.tet.2019.130666]
Access to 5-Fluoroisoxazoles via the Nitrosation of Geminal Bromo-Fluoro Arylcyclopropanes. Bondarenko, O.B.; Vinogradov, A.A.; Komarov, A.I.; Karetnikov, G.L.; Zyk, N.V.; Holt, T.; Kutateladze, A.G. Tetrahedron, 2019, 75, 2861-2865. [DOI: 10.1016/j.tet.2019.03.054]
Addressing the Challenges of Structure Elucidation in Natural Products Possessing the Oxirane Moiety. Kutateladze, A.G.; Kuznetsov, D.M.; Beloglazkina, A. A.; Holt, T. J. Org. Chem., 2018, 83, (15), 8341-8352. [DOI: 10.1021/acs.joc.8b01027] Featured Article. ACS Editors' Choice (made 20 most read JOC articles in August 2018)
Complexity-Building Exhaustive Dearomatization of Benzenoid Aromatics within an ESIPT-Initiated Three-Step Photochemical Cascade. Beduru, S.; Huple, D.B.; Kutateladze, A.G. Angew. Chem. Int. Ed. , 2024, e202415176. [DOI: 10.1002/anie.202415176]
The Discreet Structural Diversity of Briarellins: DU8+ Guided Multiple Structure Revisions Yielded Two Unknown Structural Types. Holt, T. A.; Reddy, D. S.; Huple, D. B.; West, L. M.; Rodriguez, A. D.; Crimmins, M. T.; Kutateladze, A. G. J. Org. Chem., 2020, 85, (9), 6201-6205. [DOI: 10.1021/acs.joc.0c00555]
Relativistic Force Field: Parametrization of 13C-1H Nuclear Spin-Spin Coupling Constants. Kutateladze, A.G.; Mukhina, O.A. J. Org. Chem., 2015, 80, (21), 10838-10848. [DOI: 10.1021/acs.joc.5b02001]
Photoinduced Cycloadditions in the Diversity-Oriented Synthesis Toolbox: Increasing Complexity with Straightforward Postphotochemical Modifications. Umstead, W.J.; Mukhina, O.A.; Kumar, N.N.B.; Kutateladze, A.G. Aust. J. Chem., 2015, 68, 1672-1681. [DOI: 10.1071/CH15266]
Computationally driven reassignment of the structures of aldingenins A and B. Mukhina O.A.; Koshino, H.; Crimmins M.T.; Kutateladze, A.G. Tetrahedron Lett. , 2015, 56, 4900-4903. [DOI: 10.1016/j.tetlet.2015.06.078]
Minimalist Relativistic Force Field: Prediction of Proton-Proton Coupling Constants in 1H NMR Spectra is Perfected with NBO Hybridization Parameters. Kutateladze, A.G.; Mukhina, O.A. J. Org. Chem., 2015, 80, (10), 5218-5225. [DOI: 10.1021/acs.joc.5b00619]
Photoassisted Diversity-Oriented Synthesis: Intramolecular Cycloadditions of Photogenerated Azaxylylenes with Oxazole Pendants, and Subsequent Postphotochemical Multicomponent Modifications. Kumar, N.N.B.; Kutateladze, A.G. Org. Lett., 2016, 18, (3), 460-463. [DOI: 10.1021/acs.orglett.5b03503]
Photoinduced Cycloadditions in the Diversity-Oriented Synthesis Toolbox: Increasing Complexity with Straightforward Postphotochemical Modifications. Umstead, W.J.; Mukhina, O.A.; Kumar, N.N.B.; Kutateladze, A.G. Aust. J. Chem., 2015, 68, 1672-1681. [DOI: 10.1071/CH15266]
Intramolecular Cycloadditions of Photogenerated Azaxylylenes with Oxadiazoles Provide Direct Access to Versatile Polyheterocyclic Ketopiperazines Containing a Spiro-Oxirane Moiety. Kumar, N.N.B.; Kuznetsov, D.M.; Kutateladze, A.G. Org. Lett. , 2015, 17, (3), 438-441. [DOI: 10.1021/ol5033909]
Photoinduced Intramolecular Cyclopentanation vs Photoprotolytic Oxametathesis in Policyclic Alkenes Outfitted with Conformationally Constrained Aroylmethyl Chromophores. Valiulin, R.A.; Arisco, T.M.; Kutateladze, A.G. J. Org. Chem., 2013, 78, (5), 2012-2025. [DOI: 10.1021/jo301909j]
Rapid Photoassisted Access to N,O,S-Polyheterocycles with Benzoazocine and Hydroquinoline Cores via Intramolecular Cycloadditions of Photogenerated Azaxylylenes Mukhina, O.A.; Kumar, N.N.B.; Arisco, T.M.; Valiulin, R.A.; Metzel, G.A.; Kutateladze, A.G. Angew. Chem. Int. Ed. , 2011, 50, (40), 9423-9428. [DOI: 10.1002/anie.201103597] Angewandte's Hot Paper (click here)
Double-tandem [4π+2π]-[2π+2π]-[4π+2π]-[2π+2π] Synthetic Sequence with Photoprotolytic Oxametathesis and Photoepoxidation in the Chromone Series. Valiulin, R.A.; Arisco, T.M., Kutateladze, A.G. J. Org. Chem., 2011, 76, (5), 1319-1332. [DOI: 10.1021/jo102221q]
Strained to the Limit: When a Cyclobutyl Moiety Becomes a Thermodynamic Sink in a Protolytic Ring Opening of Photogenerated Oxetanes Valiulin, R.A.; Arisco, T.M., Kutateladze, A.G. Org. Lett., 2010, 12, (15), 3398-3401. [DOI: 10.1021/ol101297b]
Photoinduced Intramolecular Cyclopentanation vs Photoprotolytic Oxametathesis in Policyclic Alkenes Outfitted with Conformationally Constrained Aroylmethyl Chromophores. Valiulin, R.A.; Arisco, T.M.; Kutateladze, A.G. J. Org. Chem., 2013, 78, (5), 2012-2025. [DOI: 10.1021/jo301909j]
Cascade Transformations Involving Thiocarbonyls: Photoassisted Access to Bicyclic Thiiranes and Oxapentalenes. Valiulin, R.A.; Kumar, N.N.B.; Kuznetsov, D.M.; Kutateladze, A.G. J. Sulfur Chem., 2013, 34, (1-2), 209-221. [DOI: 10.1080/17415993.2012.731065]
Rapid Photoassisted Access to N,O,S-Polyheterocycles with Benzoazocine and Hydroquinoline Cores via Intramolecular Cycloadditions of Photogenerated Azaxylylenes Mukhina, O.A.; Kumar, N.N.B.; Arisco, T.M.; Valiulin, R.A.; Metzel, G.A.; Kutateladze, A.G. Angew. Chem. Int. Ed. , 2011, 50, (40), 9423-9428. [DOI: 10.1002/anie.201103597] Angewandte's Hot Paper (click here)
Double-tandem [4π+2π]-[2π+2π]-[4π+2π]-[2π+2π] Synthetic Sequence with Photoprotolytic Oxametathesis and Photoepoxidation in the Chromone Series. Valiulin, R.A.; Arisco, T.M., Kutateladze, A.G. J. Org. Chem., 2011, 76, (5), 1319-1332. [DOI: 10.1021/jo102221q]
Strained to the Limit: When a Cyclobutyl Moiety Becomes a Thermodynamic Sink in a Protolytic Ring Opening of Photogenerated Oxetanes Valiulin, R.A.; Arisco, T.M., Kutateladze, A.G. Org. Lett., 2010, 12, (15), 3398-3401. [DOI: 10.1021/ol101297b]
First Example of Intramolecular [2π+2π] Alkene-Arene Photocyclization in the Chromone Series and its Synthetic Utility Valiulin, R.A.; Kutateladze, A.G. Tetrahedron Lett., 2010, 51, (29), 3803-3806. [DOI: 10.1016/j.tetlet.2010.05.078]
Harvesting the Strain Installed by a Patern?B?hi Step in a Synthetically Useful Way: High Yielding Photo-Protolytic Oxametathesis in Polycyclic Systems. Valiulin, R.A.; Kutateladze, A.G. Org. Lett., 2009, 11, (17), 3886-3889. [DOI: 10.1021/ol901456m]
Effect of Intramolecular Patern?B?hi Reaction on the Thermodynamics and Kinetics of Nearly Degenerate [3,3]-Sigmatropic Shift in Fluxional Polycycles. Valiulin, R.A.; Dressen, D.G.; Riggs, J.R.; Habte, F.M.; Kutateladze, A.G. J. Org. Chem., 2009, 74, (9), 3484-3490. [DOI: 10.1021/jo9003822]
A Peculiar Quenching Concentration Dependence of Photoinduced Fragmentation in Dithiane-Carbonyl Adducts: A Mechanistic Experimental and Theoretical Study. Valiulin, R.A.; Lakkakula, S.; Kutateladze, A.G. J. Photochem. Photobiol. A Chemistry, 2009, 206, 80-86. [DOI: 10.1016/j.jphotochem.2009.05.016]
Effect of beta-Alkylthioethyl Substitution in 1,3-Dithianes: Quasi-Anchimeric Assistance in Photoinduced Electron Transfer? Valiulin, R.A.; Kutateladze, A.G. J. Org. Chem., 2008, 73, (16), 6393-6396. [DOI: 10.1021/jo800938d]
2,6,7-Trithiabicyclo[2.2.2]octanes as Promising Photolabile Tags for Combinatorial Encoding. Valiulin, R.A.; Kutateladze, A.G. J. Org. Chem., 2008, 73, (1), 335-338. [DOI: 10.1021/jo702091e]
Interrupted Oligomerization Revisited: Simple and Efficient One Pot Multicomponent Approach to Versatile Synthetic Intermediates. Valiulin, R.A.; Halliburton, L.M.; Kutateladze, A.G. Org. Lett., 2007, 9, (20), 4061-4063. [DOI: 10.1021/ol701847b]
Method for Encoding and Screening Combinatorial Libraries. Kottani, R.; Valiulin, R. A.; Majjigapu, J. R. R., Kutateladze, A. G. WO2006US61728, 2007, June_21, esp@cenet
Photoactive Barbiturate Receptors: An Ultimate Lock-and-Key System in Which the Key Unlocks the Lock. Lakkakula, S.; Mitkin, O.D.; Valiulin, R.A.; Kutateladze, A.G. Org. Lett., 2007, 9, (6), 1077-1079. [DOI: 10.1021/ol0700153]
Direct Screening of Solution Phase Combinatorial Libraries Encoded with Externally Sensitized Photolabile Tags. Kottani, R.; Valiulin, R. A.; Kutateladze, A. G. Proc. Natl. Acad. Sci. USA, 2006, 103, (38), 13917-13921. [DOI: 10.1073/pnas.0606380103]
Conformational Analysis of Spiro-Bis-Dithiepins: a Peculiar Case of Axial Chirality Wade, E.O.; Valiulin, R.A.; Ruybal, L.A.; Kutateladze, A.G. Org. Lett., 2006, 8, (22), 5121-5124. [DOI: 10.1021/ol062172s]
When Ethyl is Infinitely Different from Methyl: Double Addition of Lithiated Dithianes to Aromatic Carboxylates Revisited. Valiulin, R. A.; Kottani, R.; Kutateladze, A. G. J. Org. Chem, 2006, 71, (13), 5047-5049. [DOI: 10.1021/jo060780f]
Externally Sensitized Deprotection of PPG-Masked Carbonyls as a Spatial Proximity Probe in Photoamplified Detection of Binding Events. Gustafson, T.P.; Metzel, G.A.; Kutateladze, A.G. Photochem. Photobiol. Sci., 2012, 11, (3), 564-577. [DOI: 10.1039/C2PP05326H]
Photochemically Amplified Detection of Molecular Recognition Events: An Ultra-Sensitive Fluorescence Turn-Off Binding Assay. Gustafson, T.P.; Metzel, G.A.; Kutateladze, A.G. Org. Biomol. Chem., 2011, 9, (13), 4752-4755. [DOI: 10.1039/C1OB05289F] Selected as an OBC HOT Article (click here)
Photoinduced Signal Amplification Through Controlled Externally Sensitized Fragmentation in Masked Sensitizers. Kottani, R.R.; Majjigapu, J.R.R.; Kurchan, A.N.; Majjigapu, K.; Gustafson, T.P.; Kutateladze, A.G. J. Am. Chem. Soc., 2006, 128, (46), 14794-14795. [DOI: 10.1021/ja066692u]
Externally Sensitized Mesolytic Fragmentations in Dithiane-Ketone Adducts. Gustafson, T. P.; Kurchan, A. N.; Kutateladze, A. G. Tetrahedron, 2006, 62, (27), 6574-6580. [DOI: 10.1016/j.tet.2006.03.065]
Release and Report: A New Photolabile Caging System with a Two-photon Fluorescence Reporting Function. Majjigapu, J. R. R.; Kurchan, A. N.; Kottani, R.; Gustafson, T. P.; Kutateladze, A. G. J. Am. Chem. Soc., 2005, 127, (36), 12458-12459. [DOI: 10.1021/ja053654m]
A Peculiar Quenching Concentration Dependence of Photoinduced Fragmentation in Dithiane-Carbonyl Adducts: A Mechanistic Experimental and Theoretical Study. Valiulin, R.A.; Lakkakula, S.; Kutateladze, A.G. J. Photochem. Photobiol. A Chemistry, 2009, 206, 80-86. [DOI: 10.1016/j.jphotochem.2009.05.016]
Photoactive Barbiturate Receptors: An Ultimate Lock-and-Key System in Which the Key Unlocks the Lock. Lakkakula, S.; Mitkin, O.D.; Valiulin, R.A.; Kutateladze, A.G. Org. Lett., 2007, 9, (6), 1077-1079. [DOI: 10.1021/ol0700153]
Photoinduced signal amplification through externally sensitized photofragmentation in masked photosensitizers. Kutateladze, A. G.; Kurchan, A. N.; Kottani, R.; Majjigapu, J. R. R. US 8,735,167 B2, 2014, May27.
Method for Encoding and Screening Combinatorial Libraries. Kottani, R.; Valiulin, R. A.; Majjigapu, J. R. R., Kutateladze, A. G. WO2006US61728, 2007, June_21, esp@cenet
Photolabile system with instantaneous fluorescence reporting function. Kutateladze, A. G.; Kurchan, A. N.; Kottani, R.; Majjigapu, J. R. R. WO2007008471 , 2007, January_18, esp@cenet
Photoinduced Signal Amplification Through Controlled Externally Sensitized Fragmentation in Masked Sensitizers. Kottani, R.R.; Majjigapu, J.R.R.; Kurchan, A.N.; Majjigapu, K.; Gustafson, T.P.; Kutateladze, A.G. J. Am. Chem. Soc., 2006, 128, (46), 14794-14795. [DOI: 10.1021/ja066692u]
Direct Screening of Solution Phase Combinatorial Libraries Encoded with Externally Sensitized Photolabile Tags. Kottani, R.; Valiulin, R. A.; Kutateladze, A. G. Proc. Natl. Acad. Sci. USA, 2006, 103, (38), 13917-13921. [DOI: 10.1073/pnas.0606380103]
When Ethyl is Infinitely Different from Methyl: Double Addition of Lithiated Dithianes to Aromatic Carboxylates Revisited. Valiulin, R. A.; Kottani, R.; Kutateladze, A. G. J. Org. Chem, 2006, 71, (13), 5047-5049. [DOI: 10.1021/jo060780f]
Release and Report: A New Photolabile Caging System with a Two-photon Fluorescence Reporting Function. Majjigapu, J. R. R.; Kurchan, A. N.; Kottani, R.; Gustafson, T. P.; Kutateladze, A. G. J. Am. Chem. Soc., 2005, 127, (36), 12458-12459. [DOI: 10.1021/ja053654m]
Dithiane, Trithiane and Dithiazane-Based Photolabile Scaffolds for Molecular Recognition: Mechanism and Efficiency of the Photoinduced Fragmentation in Aqueous Reductive Environments. Kutateladze, A.G; Kottani, R.; Kurchan, A. N.; Majjigapu, J. R. R.; Shirk, S. M. Phosph. Sulf. Silicon, 2005, 180, (5-6), 1379-1384.
Photoinduced signal amplification through externally sensitized photofragmentation in masked photosensitizers. Kutateladze, A. G.; Kurchan, A. N.; Kottani, R.; Majjigapu, J. R. R. US 8,735,167 B2, 2014, May27.
Photolabile Amphiphiles with Fluorogenic Thioxanthone-Dithiane Functionality: Synthesis and Photoinduced Fragmentation in Micelles. Ezhov, R.N.; Rozhkov, V.V.; Majjigapu, J.R.R.; Kutateladze, A.G. J. Sulf. Chem., 2008, 29, (3-4), 389-400. [DOI: 10.1080/17415990802027289]
Photoamplification and Multiple Tag Release in a Linear Peptide-Based Array of Dithiane Adducts Majjigapu, K.; Majjigapu, J.R.R.; Kutateladze, A.G. Angew. Chem., 2007, 46, (32), 6137-6140. [DOI: 10.1002/anie.200701512]
Method for Encoding and Screening Combinatorial Libraries. Kottani, R.; Valiulin, R. A.; Majjigapu, J. R. R., Kutateladze, A. G. WO2006US61728, 2007, June_21, esp@cenet
Photolabile system with instantaneous fluorescence reporting function. Kutateladze, A. G.; Kurchan, A. N.; Kottani, R.; Majjigapu, J. R. R. WO2007008471 , 2007, January_18, esp@cenet
Photoinduced Signal Amplification Through Controlled Externally Sensitized Fragmentation in Masked Sensitizers. Kottani, R.R.; Majjigapu, J.R.R.; Kurchan, A.N.; Majjigapu, K.; Gustafson, T.P.; Kutateladze, A.G. J. Am. Chem. Soc., 2006, 128, (46), 14794-14795. [DOI: 10.1021/ja066692u]
Release and Report: A New Photolabile Caging System with a Two-photon Fluorescence Reporting Function. Majjigapu, J. R. R.; Kurchan, A. N.; Kottani, R.; Gustafson, T. P.; Kutateladze, A. G. J. Am. Chem. Soc., 2005, 127, (36), 12458-12459. [DOI: 10.1021/ja053654m]
Dithiane, Trithiane and Dithiazane-Based Photolabile Scaffolds for Molecular Recognition: Mechanism and Efficiency of the Photoinduced Fragmentation in Aqueous Reductive Environments. Kutateladze, A.G; Kottani, R.; Kurchan, A. N.; Majjigapu, J. R. R.; Shirk, S. M. Phosph. Sulf. Silicon, 2005, 180, (5-6), 1379-1384.
Photoamplification and Multiple Tag Release in a Linear Peptide-Based Array of Dithiane Adducts Majjigapu, K.; Majjigapu, J.R.R.; Kutateladze, A.G. Angew. Chem., 2007, 46, (32), 6137-6140. [DOI: 10.1002/anie.200701512]
Photoinduced Signal Amplification Through Controlled Externally Sensitized Fragmentation in Masked Sensitizers. Kottani, R.R.; Majjigapu, J.R.R.; Kurchan, A.N.; Majjigapu, K.; Gustafson, T.P.; Kutateladze, A.G. J. Am. Chem. Soc., 2006, 128, (46), 14794-14795. [DOI: 10.1021/ja066692u]
Photoinduced signal amplification through externally sensitized photofragmentation in masked photosensitizers. Kutateladze, A. G.; Kurchan, A. N.; Kottani, R.; Majjigapu, J. R. R. US 8,735,167 B2, 2014, May27.
Photolabile system with instantaneous fluorescence reporting function. Kutateladze, A. G.; Kurchan, A. N.; Kottani, R.; Majjigapu, J. R. R. WO2007008471 , 2007, January_18, esp@cenet
Photoinduced Signal Amplification Through Controlled Externally Sensitized Fragmentation in Masked Sensitizers. Kottani, R.R.; Majjigapu, J.R.R.; Kurchan, A.N.; Majjigapu, K.; Gustafson, T.P.; Kutateladze, A.G. J. Am. Chem. Soc., 2006, 128, (46), 14794-14795. [DOI: 10.1021/ja066692u]
Externally Sensitized Mesolytic Fragmentations in Dithiane-Ketone Adducts. Gustafson, T. P.; Kurchan, A. N.; Kutateladze, A. G. Tetrahedron, 2006, 62, (27), 6574-6580. [DOI: 10.1016/j.tet.2006.03.065]
Release and Report: A New Photolabile Caging System with a Two-photon Fluorescence Reporting Function. Majjigapu, J. R. R.; Kurchan, A. N.; Kottani, R.; Gustafson, T. P.; Kutateladze, A. G. J. Am. Chem. Soc., 2005, 127, (36), 12458-12459. [DOI: 10.1021/ja053654m]
Dithiane and Trithiane-Based Photolabile Molecular Linkers Equipped with Amino-Functionality: Synthesis and Quantum Yields of Fragmentation. Kurchan, A. N.; Mitkin, O. D.; Kutateladze, A. G. J. Photochem. Photobiol. A: Chemistry, 2005, 171, 121-129. [DOI: 10.1016/j.jphotochem.2004.09.014]
Dithiane, Trithiane and Dithiazane-Based Photolabile Scaffolds for Molecular Recognition: Mechanism and Efficiency of the Photoinduced Fragmentation in Aqueous Reductive Environments. Kutateladze, A.G; Kottani, R.; Kurchan, A. N.; Majjigapu, J. R. R.; Shirk, S. M. Phosph. Sulf. Silicon, 2005, 180, (5-6), 1379-1384.
Addition of Lithiated 5 Hydroxymethyl-1,3 Dithiane to Benzaldehyde: HMPA-Controlled trans-Stereoselectivity Li, Z.; Kurchan, A. N.; Kutateladze, A. G. Org. Lett., 2004, 6, (8), 1213-1216. [DOI: 10.1021/ol0499497]
Dithiane and Trithiane-Based Photocleavable Systems for Molecular Assembly and Disassembly. Kurchan, A. N.; Shirk, S. M.; Kutateladze, A. G. The Spectrum, 2004, 17, (4), 20-25.
Novel Dithia-aza-norbornanes as "Stiff" Bicyclic Dithiazines. Kurchan, A. N.; Wade, E.; Kutateladze, A. G. Synlett , 2003, (11), 1731-1733. [DOI: 10.1055/s-2003-41431]
Amino Acid-Based Dithiazines: Synthesis and Photofragmentation of Their Benzaldehyde Adducts. Kurchan, A. N.; Kutateladze, A. G. Org. Lett., 2002, 4, (23), 4129-4131. [DOI: 10.1021/ol0268790]
Synthesis of Dithiane-Based Photolabile Molecular Systems. Mitkin, O.; Wan, Y.; Kurchan, A.; Kutateladze, A. Synthesis, 2001, (8), 1133-1142.
Dithiane and Trithiane-Based Photolabile Scaffolds for Molecular Recognition. Mitkin, O. D.; Kurchan, A. N.; Wan, Y.; Schiwal, B. F.; Kutateladze, A. G. Org. Lett., 2001, 3, (12), 1841-1844. [DOI: 10.1021/ol015933u]
Photoinduced 1,3-Proton Shift in Methyldithiepines as a Potential Way of Modulating Hyperpolarizabilities. Wan, Y.; Kurchan, A. N.; Kutateladze, A. G. J. Org. Chem., 2001, 66, (5), 1894-1899. [DOI: 10.1021/jo005707i]
Direct Transformation of 1,3-Dihalides into Dithianes and Dithiepins via a Novel One Pot Reaction with Carbon Disulfide and Sodium Borohydride. Wan, Y.; Kurchan, A. N.; Barnhurst L. A.; Kutateladze, A. G. Org. Lett., 2000, 2, (8), 1133-1135. [DOI: 10.1021/ol005705k]
Dithiane, Trithiane and Dithiazane-Based Photolabile Scaffolds for Molecular Recognition: Mechanism and Efficiency of the Photoinduced Fragmentation in Aqueous Reductive Environments. Kutateladze, A.G; Kottani, R.; Kurchan, A. N.; Majjigapu, J. R. R.; Shirk, S. M. Phosph. Sulf. Silicon, 2005, 180, (5-6), 1379-1384.
Dithiane and Trithiane-Based Photocleavable Systems for Molecular Assembly and Disassembly. Kurchan, A. N.; Shirk, S. M.; Kutateladze, A. G. The Spectrum, 2004, 17, (4), 20-25.
Photoactive Barbiturate Receptors: An Ultimate Lock-and-Key System in Which the Key Unlocks the Lock. Lakkakula, S.; Mitkin, O.D.; Valiulin, R.A.; Kutateladze, A.G. Org. Lett., 2007, 9, (6), 1077-1079. [DOI: 10.1021/ol0700153]
Dithiane and Trithiane-Based Photolabile Molecular Linkers Equipped with Amino-Functionality: Synthesis and Quantum Yields of Fragmentation. Kurchan, A. N.; Mitkin, O. D.; Kutateladze, A. G. J. Photochem. Photobiol. A: Chemistry, 2005, 171, 121-129. [DOI: 10.1016/j.jphotochem.2004.09.014]
Synthesis of Dithiane-Based Photolabile Molecular Systems. Mitkin, O.; Wan, Y.; Kurchan, A.; Kutateladze, A. Synthesis, 2001, (8), 1133-1142.
Dithiane and Trithiane-Based Photolabile Scaffolds for Molecular Recognition. Mitkin, O. D.; Kurchan, A. N.; Wan, Y.; Schiwal, B. F.; Kutateladze, A. G. Org. Lett., 2001, 3, (12), 1841-1844. [DOI: 10.1021/ol015933u]
Synthesis and Liquid Membrane Transport Properties of Photolabile Molecular Clips Based on Dithiane-Spiro-Crown Ethers. Barnhurst, L. A.; Kutateladze, A. G. Org. Lett., 2001, 3, (17), 2633-2635. [DOI: 10.1021/ol016309k]
Photoinduced C-C Bond Cleavage in Dithiane-Carbonyl Adducts: A Laser Flash Photolysis Study. Vath, P.; Falvey, D. E.; Barnhurst, L. A.; Kutateladze, A. G. J. Org. Chem., 2001, 66, (8), 2886-2890. [DOI: 10.1021/jo010102n]
Direct Transformation of 1,3-Dihalides into Dithianes and Dithiepins via a Novel One Pot Reaction with Carbon Disulfide and Sodium Borohydride. Wan, Y.; Kurchan, A. N.; Barnhurst L. A.; Kutateladze, A. G. Org. Lett., 2000, 2, (8), 1133-1135. [DOI: 10.1021/ol005705k]
Efficient Electrochemical Deprotection of Carboxylic and Amino Acids from Their 2-(Hydroxymethyl)-1,3-dithiane (Dim) Esters. Barnhurst, L. A.; Wan, Y.; Kutateladze A. G. Org. Lett. , 2000, 2, (6), 799-801. [DOI: 10.1021/ol005537w]
Photooxidation of Methyldithiepins into Dithiepin Carboxaldehydes in Carbon Tetrachloride. Wan Y., Barnhurst, L. A.; Kutateladze A. G. Org. Lett. , 1999, 1, (6), 937-939. [DOI: 10.1021/ol990870p]
Reactions of Nitrosonium Ethyl Sulfate with Olefins and Dienes: An Experimental and Theoretical Study. Zyk, N. V.; Nesterov, E. E.; Khlobystov, A. N.; Zefirov, N. S.; Barnhurst, L. A.; Kutateladze, A. G. J. Org. Chem. , 1999, 64, (19), 7121-7128. [DOI: 10.1021/jo990679t]
Dithiane-Based Photolabile Amphiphiles: Toward Photolabile Liposomes. Li, Z.; Wan, Y.; Kutateladze, A. G. Langmuir, 2003, 19, (16), 6381-6391. [DOI: 10.1021/la034188m]
Liposomes from Novel Photolabile Phospholipids: Light-Induced Unloading of Small Molecules as Monitored by PFG NMR. Wan, Y.; Angleson, J. K.; Kutateladze, A. G. J. Am. Chem. Soc., 2002, 124, (20), 5610-5611. [DOI: 10.1021/ja016874i]
Synthesis of Dithiane-Based Photolabile Molecular Systems. Mitkin, O.; Wan, Y.; Kurchan, A.; Kutateladze, A. Synthesis, 2001, (8), 1133-1142.
Dithiane and Trithiane-Based Photolabile Scaffolds for Molecular Recognition. Mitkin, O. D.; Kurchan, A. N.; Wan, Y.; Schiwal, B. F.; Kutateladze, A. G. Org. Lett., 2001, 3, (12), 1841-1844. [DOI: 10.1021/ol015933u]
Photoinduced 1,3-Proton Shift in Methyldithiepines as a Potential Way of Modulating Hyperpolarizabilities. Wan, Y.; Kurchan, A. N.; Kutateladze, A. G. J. Org. Chem., 2001, 66, (5), 1894-1899. [DOI: 10.1021/jo005707i]
Direct Transformation of 1,3-Dihalides into Dithianes and Dithiepins via a Novel One Pot Reaction with Carbon Disulfide and Sodium Borohydride. Wan, Y.; Kurchan, A. N.; Barnhurst L. A.; Kutateladze, A. G. Org. Lett., 2000, 2, (8), 1133-1135. [DOI: 10.1021/ol005705k]
Efficient Electrochemical Deprotection of Carboxylic and Amino Acids from Their 2-(Hydroxymethyl)-1,3-dithiane (Dim) Esters. Barnhurst, L. A.; Wan, Y.; Kutateladze A. G. Org. Lett. , 2000, 2, (6), 799-801. [DOI: 10.1021/ol005537w]
Photooxidation of Methyldithiepins into Dithiepin Carboxaldehydes in Carbon Tetrachloride. Wan Y., Barnhurst, L. A.; Kutateladze A. G. Org. Lett. , 1999, 1, (6), 937-939. [DOI: 10.1021/ol990870p]
Toward Parameterization of Spin-Orbit Coupling in Triplet Organic Diradicals Separated by a Partially Conjugated Spacer. Kutateladze, A.G.; McHale, W.A.Jr. ARKIVOC, 2005, IV, 88-101.
An Efficient Photo-SET-Induced Cleavage of Dithiane-Carbonyl Adducts and Its Relevance to the Development of Photoremovable Protecting Groups for Ketones and Aldehydes. McHale, W. A.; Kutateladze A. G. J. Org. Chem. , 1998, 63, (26), 9924-9931. [DOI: 10.1021/jo981697y]
Tin-Free Reductive Photochemical Carboxymethylation of Olefins with α-Alkylthioacetates. Deng, L. X.; Kutateladze, A. G. Tetrahedron Lett. , 1997, 38, (44), 7829-7832.
Dithiane and Trithiane-Based Photolabile Scaffolds for Molecular Recognition. Mitkin, O. D.; Kurchan, A. N.; Wan, Y.; Schiwal, B. F.; Kutateladze, A. G. Org. Lett., 2001, 3, (12), 1841-1844. [DOI: 10.1021/ol015933u]